PNF222, poly[[1,2,3,6,7,8-hexahydro-2,7-bis(2-octyldodecyl)-1,3,6,8-tetraoxobenzophenanthroline-4,9-diyl](3,3"-difluoro[2,2"-bithiophene]-5,5"-diyl)], is commonly used as polymer acceptor in all polymer solar cells or OFETs material.
Compared to PNDI(2OD)2T, with the introduction of the fluorine atoms on the electronic structure of the polymer, PNF222 has lower electronic energy levels due to the strong electronegativity of its fluorine atoms. In turn, this results in higher Voc, Jsc and FF for OPV devices.
It has also been reported that PCE of Si-PEDOT:PSS solar cells was promoted from 12.6% to 14.5% while a PNF222 polymer interlayer was incorporated, with the polymer orientation playing a critical role on the polymer–Si contact quality [3].
Luminosyn™ PNF222
Luminosyn™ PNF222 is now available.
High molecular weight and high purityPNF222 is purified by soxhlet extraction with methanol, hexane and chlorobenzene under argon atmosphere
Batch-specific GPC dataHave confidence in what you are ordering; batch-specific GPC data for your thesis or publications
Large quantity ordersPlan your experiments with confidence with polymers from the same batch
General Information
| Full name | Poly[[1,2,3,6,7,8-hexahydro-2,7-bis(2-octyldodecyl)-1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-4,9-diyl](3,3"-difluoro[2,2"-bithiophene]-5,5"-diyl)] |
| Synonyms | PNDI-2F, P(NDI2OD-T2F), PNDI(2OD)2T-2F, P(NDI2OD-FT2) |
| CAS number | 1773524-46-1 |
| Chemical formula | (C62H86F2N2O4S2)n |
| Molecular weight | See Batch Details table above |
| HOMO / LUMO | HOMO = - 5.99 eV, LUMO = - 3.90 eV [1] |
| Suggesting solvents | Chlorobenzene, dichlorobenzene |
| Classification / Family | PNDI polymers, Bithiophene, Heterocyclic five-membered ring, Organic semiconducting materials, Low band gap polymers, Non-fullerene acceptors (NFAs), Organic photovoltaics, All-polymer solar cells, OFETs |
Chemical Structure
MSDS Documentation
PNF222 MSDS Sheet
Pricing
| Batch | Quantity | Price |
| M2052A2 | 50 mg | ]]£231.00 |
| M2052A2 | 100 mg | £370.00 |
| M2052A2 | 250 mg | £739.00 |
| M2052A2 | 500 mg | £1330.00 |
| M2052A2 | 1 g | £2390.00 |
| M2052A2 | 5 g / 10 g* | Please enquire |
*for 5 - 10 grams order quantity, the lead time is 4-6 weeks.
Batch Details
| Batch | Mw | Mn | PDI | Stock Info |
| M2052A1 | 98,436 | 55,594 | 1.77 | Discontinued |
| M2052A2 | 163,267 | 81,850 | 1.99 | In Stock |
Literature and Reviews
- Controlling Energy Levels and Blend Morphology for All-Polymer Solar Cells via Fluorination of a Naphthalene Diimide-Based Copolymer Acceptor, M. A. Uddin et al., Macromolecules, 49 (17), 6374–6383 (2016); DOI: 10.1021/acs.macromol.6b01414.
- Fluoro-Substituted n-Type Conjugated Polymers for Additive-Free All-Polymer Bulk Heterojunction Solar Cells with High Power Conversion Efficiency of 6.71%, J. Jung et al., Adv. Mater., 27, 3310–3317 (2015); DOI: 10.1002/adma.20150121.
- Naphthalene Diimide-Based n-Type Polymers: Efficient Rear Interlayers for High-Performance Silicon–Organic Heterojunction Solar Cells, Y. Han et al., ACS Nano, 11 (7), 7215–7222 (2017); DOI: 10.1021/acsnano.7b03090.
- Bulk Electron Transport and Charge Injection in a High Mobility n-Type Semiconducting Polymer, R. Steyrleuthner et al., Adv. Mater., 22, 2799–2803 (2010); DOI: 10.1002/adma.201000232.n2200.
To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.
