10,10′-(sulfonylbis(4,1-phenylene))bis(10H-phenoxazine) (PXZ-DPS), posses a structure of a weak electron-accepting diphenylsulfone and strong electron-donating acridine moieties. It is used as a TADF green emitter or dopant, and has a small ΔEST of less than 0.1 eV, a short lifetime of less than 3.1 µs.
Like DMAC-DPS, PXZ-DPS has high photo-luminescence quantum yields (PLQY) in devices even with the change of host materials. It is an ideal candidate for applications in green TADF-OLED devices with biploar charge-transporting capability.
General Information
| CAS number | 1477511-57-1 |
| Full name | 10-(4-(4-(10H-Phenoxazin-10-yl)phenylsulfonyl)phenyl)-10H-phenoxazine |
| Chemical formula | C36H24N2O4S |
| Molecular weight | 580.65 g/mol |
| Absorption | n/a |
| PL | λem 507 nm in toluene |
| HOMO/LUMO | HOMO = 5.59 eV, LUMO = 2.79 eV; T1=2.74 eV, ΔEST = 0.08 eV [1] |
| Synonyms | DPS-PXZ |
| Classification / Family | Acridine derivatives, TADF green emitter, TADF green host materials, Phosphorescent organic light-emitting devices (PHOLEDs), Sublimed materials |
Product Details
| Purity | Sublimed >99.0% (HPLC) |
| Melting point | TGA > 220 °C (0.5% weight loss) |
| Appearance | Off-white powder/crystals |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.
Chemical Structure
Device Structure(s)
| Device structure | ITO/a-NPD (30 nm)/TCTA (20 nm)/CzSi (10 nm)/PXZ–DPS:DPEPO (20 nm)/DPEPO (10 nm)/TPBI (30 nm)/LiF (1 nm)/Al [2] |
| Colour | Green  |
| Max EQE | 17.6% |
| Device structure | >ITO/TAPC (30 nm)/TCTA (10 nm)/PXZ-DPS:0.5 mol% PhtBuPAD* (30 nm)/BPBiPA (40 nm)/LiF (0.5 nm)/Al (150 nm) [2] |
| Colour | Green |
| Max EQE | 19.3% |
| Max. Power Efficiency | 48.5 lm W-1 |
| Device structure | ITO/TAPC (30 nm)/TCTA (10 nm)/PXZ-DPS:PhCzTRz:0.5 mol% PhtBuPAD* (30 nm)/BPBiPA (40 nm)/LiF (0.5 nm)/Al (150 nm) [2] |
| Colour | Green |
| Max EQE | 24% |
| Max. Power Efficiency | 71.4 lm W-1 |
*For chemical structure information, please refer to the cited references.
Pricing
| Grade | Order Code | Quantity | Price |
| Sublimed (>99.0% purity) | M2122A1 | 250 mg | £270.00 |
| Sublimed (>99.0% purity) | M2122A1 | 500 mg | £464.00 |
| Sublimed (>99.0% purity) | M2122A1 | 1 g | £742.00 |
MSDS Documentation
PXZ-DPS MSDS sheet
Literature and Reviews
- Efficient blue organic light-emitting diodes employing thermally activated delayed fluorescence, Q. Zhang et al., Nat. Photonics, 8, 326–332 (2014); DOI: 10.1038/nphoton.2014.12.
- Blocking Energy-Loss Pathways for Ideal Fluorescent Organic Light-Emitting Diodes with Thermally Activated Delayed Fluorescent Sensitizers, D. Zhang et al., Adv. Mater., 30, 1705250(2018); DOI: 10.1002/adma.201705250.
- Recent progress of green thermally activated delayed fluorescent emitters, Y. Im et al., J. Info. Display, 18:3, 101-117 (2017); DOI: 10.1080/15980316.2017.1333046.
To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.
